Merck 106049 2500 Dichloromethane Empruve 2,5 LT.

Merck 106049 2500 Dichloromethane Empruve 2,5 LT.

81.07 ( KDV Dahil )

EMPROVE® ESSENTIAL Ph Eur,BP,NF CAS #: 75-09-2 EC Number: 200-838-9

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Description
Catalogue Number 106049
Synonyms DCM, Methylene chloride, Methylene dichloride
Description Dichloromethane

Product Information
CAS number 75-09-2
EC index number 602-004-00-3
EC number 200-838-9
Grade Ph Eur,BP,NF
Hill Formula CH₂Cl₂
Chemical formula CH₂Cl₂
Molar Mass 84.93 g/mol
HS Code 2903 12 00
Structure formula Image Structure formula Image
Quality Level MQ500

Physicochemical Information
Boiling point 40 °C (1013 hPa)
Density 1.33 g/cm3 (20 °C)
Evaporation number 1.9
Explosion limit 13 – 22 %(V)
Ignition temperature 605 °C DIN 51794
Melting Point -95 °C
Vapor pressure 584 hPa (25 °C)
Solubility 20 g/l

Toxicological Information
LD 50 oral LD50 Rat 1600 mg/kg
LD 50 dermal LD50 Rat > 2000 mg/kg

Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s) H315: Causes skin irritation.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
Precautionary Statement(s) P202: Do not handle until all safety precautions have been read and understood.
P261: Avoid breathing mist or vapours.
P264: Wash skin thoroughly after handling.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Signal Word Warning
RTECS PA8050000
Storage class 6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK WGK 2 obviously hazardous to water
Disposal 2
Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).

Safety Information
Categories of danger carcinogenic

Storage and Shipping Information
Storage Store at +2°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID UN 1593 , 6.1, III
Declaration (transport by air) IATA-DGR UN 1593 , 6.1, III
Declaration (transport by sea) IMDG-Code UN 1593 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)

Specifications
Purity (GC) ≥ 99.0 %
Identity (IR) conforms
Appearance of the substance conforms
Acidic substances conforms
Acidity (HCl) ≤ 0.001 %
Density (d 20 °C/20 °C) 1.320 – 1.332
Density (d 25 °C/25 °C) 1.318 – 1.322
Refractive index (n 20/D) 1.423 – 1.425
Free chlorine (Cl) conforms
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Ethanol) ≤ 2.0 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (2-Methyl-2-buten) ≤ 0.03 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Carbon tetrachloride (impurity A)) ≤ 0.001 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Chloroform (impurity B)) ≤ 0.005 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Total of impurities other than ethanol and 2-methyl-2-butene) ≤ 0.1 % (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC)(reportingthreshold) ≤ 0.005 % (v/v)
1,1-Dichloroethene (GC) ≤ 0.03 %
1,2-Dichloroethene (GC) ≤ 0.03 %
Other residual solvents (ICH Q3C) excluded by manufacturing process
Evaporation residue ≤ 0.002 %
Water ≤ 0.020 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities).
Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
The product is stabilized with about 50 ppm 2-Methyl-2-butene.
Conforms to Ph Eur, BP, NF.
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